Heterogeneous Enantioselective Hydrogenation: Theory and Practice (Catalysis by !!!!l Complexes)

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Heterogeneous Enantioselective Hydrogenation: Theory and Practice (Catalysis by !!!!l Complexes)
By Evgenii Klabunovskii, Gerard V. Smith, Ágnes Zsigmond

Publisher:
Springer
Number Of Pages: 304
Publication Date: 2006-10-05
ISBN-10 / ASIN: 1402042949
ISBN-13 / EAN: 9781402042942
Binding: Hardcover

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Heterogeneous Enantioselective Hydrogenation: Theory and Practice reviews the development of enantioselective hydrogenation reaction catalysts. It looks at the first relatively ineffective catalysts right through to modern highly effective enantioselective catalytic systems, comparable in their efficiency to chiral !!!!l complexes and enzymatic systems. The book begins with a summary of the first work on heterogeneous !!!!l catalysts, which showed only the principal possibilities of enantioselective reactions. It then elaborates on !!!!l catalysts which have enantioselectivities close to 100%. Finally, the practical utilization of chiral catalytic systems in processes of hydrogenation is described. The alpha- and beta-hydroxy carboxylic acid esters produced are precursors for manufacturing many synthones used for medicines as well as for monomers used for biodegradable polyesters, both of which have important practical applications.

The volume summarizes more than 800 scientific papers in the field of enantioselective catalytic hydrogenation reactions, mainly those using heterogeneous !!!!l catalysts. It provides detailed explanations of special techniques for the preparation of effective dissymmetric catalysts which provide highly efficient catalytic systems. This book differs from previous publications by virtue of the recommendations for the practical utilization of recently described preparations of !!!!l catalysts.

This book will be an invaluable resource to catalysis researchers as well as to those utilizing the technology.
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